Chemistry:Phoxim

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Phoxim[1]
Phoxim-2D-by-AHRLS-2012.png
Phoxim-3D-balls-by-AHRLS-2012.png
Names
IUPAC name
(E,Z)-N-[(Diethoxyphosphorothioyl)oxy]benzenecarboximidoyl cyanide
Other names
Baythion
Valexone
Phoxime
Sebacil
Valexon
Volaton
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 238-887-3
KEGG
MeSH Phoxim
UNII
Properties
C12H15N2O3PS
Molar mass 298.30 g·mol−1
Appearance Brownish red liquid
Density 1.17 g/cm3
Melting point 6.1 °C (43.0 °F; 279.2 K)
Boiling point 102
7 ppm
Pharmacology
1=ATCvet code} QP53AE03 (WHO)
Hazards
GHS pictograms GHS07: HarmfulGHS08: Health hazardGHS09: Environmental hazard
GHS Signal word Warning
H302, H317, H361f, H410
P201, P202, P261, P264, P270, P272, P273, P280, P281, P301+312, P302+352, P308+313, P321, P330, P333+313, P363, P391, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Tracking categories (test):

Phoxim is an organophosphate insecticide that is produced by the Bayer corporation. It is an analogous dimethyl ester and an organothiophosphate acaricide. It is allowed for use in limited applications in the European Union.[2] It is banned for use on crops in the European Union since 22 December 2007.[3]

It is used in veterinary medicine to treat ectoparasitic acarids.

This pesticide should be used with caution since some insects like Helicoverpa assulta become even more resistant when exposed.[4]

References

  1. "Phoxim PubChem entry". https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=9570290&loc=ec_rcs. 
  2. Commission for Veterinary Medicinal Products; Phoxim Summary Report
  3. COMMISSION DECISION of 21 June 2007 concerning the non-inclusion of certain active substances in Annex I to Council Directive 91/414/EEC and the withdrawal of authorisations for plant protection products containing these substances
  4. Wang, Kai-Yun; Zhang, Yong; Wang, Hong-Yan; Xia, Xiao-Ming; Liu, Tong-Xian (2010-01-01). "Influence of three diets on susceptibility of selected insecticides and activities of detoxification esterases of Helicoverpa assulta (Lepidoptera: Noctuidae)". Pesticide Biochemistry and Physiology 96 (1): 51–55. doi:10.1016/j.pestbp.2009.09.003. 

External links

  • Phoxim in the Pesticide Properties DataBase (PPDB)