Chemistry:Lithium hexafluorogermanate
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Names | |
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IUPAC name
Lithium hexafluorogermanate
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Other names
Lithium germanium fluoride
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Identifiers | |
3D model (JSmol)
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PubChem CID
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Properties | |
Li2GeF6 | |
Molar mass | 200.51 g/mol |
Appearance | white solid |
Melting point | 510 °C (950 °F; 783 K) |
53.9 g / 100 g water (25°C) | |
Hazards | |
Safety data sheet | External MSDS |
NFPA 704 (fire diamond) | |
Related compounds | |
Related compounds
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Gadolinium oxysulfide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Lithium hexafluorogermanate is the inorganic compound with the formula Li2GeF6. It forms a solid off-white deliquescent powder. When exposed to moisture, it easily hydrolyses to release hydrogen fluoride and germanium tetrafluoride gases.[1]
Reactions and applications
Lithium hexafluorogermanate can be dissolved in a solution of hydrogen fluoride, which forms a precipitate of lithium fluoride.[2]
It can be used as a densification aid in the sintering of gadolinium oxysulfide,[3][4] and as a lithium salt additive in a lithium-ion battery electrolyte.[5]
References
- ↑ "Lithium Hexafluorogermanate Safety Data Sheet". Lorad Chemical Corporation. http://loradchemical.com/data/sds/SDS-Lithium-Hexafluorogermanate.pdf. Retrieved 2017-09-20.
- ↑ Tychinskaya, I.I., Opalovskii, A.A. & Nikolaev, N.S. Russ Chem Bull (1965) 14: 725. https://doi.org/10.1007/BF00846742
- ↑ L. S. Bolyasnikova, V. A. Demidenko, S. B. Eron'ko, O. P. Ovsyannikova, and S. B. Mikhrin, "Gd2O2S:Pr:Ce Optical Scintillation Ceramics and their Properties," J. Opt. Technol. 73, 138-142 (2006).
- ↑ "Lithium Hexafluorogermanate". Lorad Chemical Corporation. http://loradchemical.com/products/lithium-hexafluorogermanate. Retrieved 2017-09-19.
- ↑ "Lithium-ion battery electrolyte" CN patent application 103326066, published 2013-09-25, assigned to Suzhou Nuoxin Innovation Energy Co. Ltd.
Original source: https://en.wikipedia.org/wiki/Lithium hexafluorogermanate.
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