Chemistry:Lithium hexafluorostannate
From HandWiki
| Names | |
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| IUPAC name
Dilithium hexafluorostannate(2-)
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
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| Properties | |
| F6Li2Sn | |
| Molar mass | 246.58 g·mol−1 |
| Appearance | White powder |
| Density | g/cm3 |
| Insoluble | |
| Hazards | |
| GHS Signal word | Danger |
| H301, H315, H319, H335 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Lithium hexafluorostannate is an inorganic chemical compound with the chemical formula Li
2SnF
6.[1][2]
Synthesis
The compound can be prepared by reacting ammonium hexachlorostannate, lithium carbonate, and fluorine gas at 400 °C,[3] or by reacting lithium stannate with hydrofluoric acid.[4]
Physical properties
The compound forms white crystals of the monoclinic system.[5][6]
Lithium hexafluorostannate forms a dihydrate.[7]
References
- ↑ "Lithium Hexafluorostannate(IV)" (in en). https://www.americanelements.com/lithium-hexafluorostannate-iv-17029-16-2.
- ↑ "Lithium (CAS Number 17029-16-2) : Strem Product Catalog". strem.com. https://www.strem.com/catalog/v/93-0327/36/lithium_17029-16-2.
- ↑ Wilde, W.; Kolditz, L. (November 1987). "Über das thermische Verhalten einiger Lithium‐und Natriumhexafluorometallate(IV)". Zeitschrift für anorganische und allgemeine Chemie 554 (11): 205–216. doi:10.1002/zaac.19875541127. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19875541127. Retrieved 25 June 2024.
- ↑ Hebecker, Christoph; Hoppe, Rudolf (1 January 1966). "Neue Untersuchungen an komplexen Fluoriden von Zinn und Blei [1"] (in de). Naturwissenschaften 53 (4): 106–106. doi:10.1007/BF00601472. ISSN 1432-1904. https://link.springer.com/article/10.1007/BF00601472. Retrieved 25 June 2024.
- ↑ Donnay, Joseph Désiré Hubert (1973) (in en). Crystal Data: Inorganic compounds. National Bureau of Standards. p. M-163. https://books.google.com/books?id=5lVCBwmZsLYC&dq=lithium+hexafluorostannate&pg=RA2-PA163. Retrieved 23 June 2024.
- ↑ Haynes, William M. (9 June 2015) (in en). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. p. 4-72. ISBN 978-1-4822-6097-7. https://books.google.com/books?id=RpLYCQAAQBAJ&dq=lithium+hexafluorostannate&pg=SA4-PA72. Retrieved 23 June 2024.
- ↑ Marseglia, E. A.; Brown, I. D. (15 June 1973). "Lithium hexafluorotitanate dihydrate and lithium hexafluorostannate dihydrate" (in en). Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry 29 (6): 1352–1354. doi:10.1107/S0567740873004498. ISSN 0567-7408. https://journals.iucr.org/paper?S0567740873004498. Retrieved 23 June 2024.
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