Chemistry:Pentaoxygen difluoride

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Pentaoxygen difluoride
Pentaoxygen difluoride.svg
Identifiers
3D model (JSmol)
Properties
F2O5
Molar mass 117.992 g·mol−1
Appearance reddish-brown liquid at 90 K
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

Pentaoxygen difluoride is a binary inorganic compound of fluorine and oxygen with the chemical formula O
5
F
2
.[1][2] The compound is one of many known oxygen fluorides.

Synthesis

The compound can be prepared by electric discharges through the F
2
O
2
mixture of the certain molar ratio at 60 to 77 K. The ratio is predicted to be 5:2.[3]

Physical properties

Pentaoxygen difluoride is an oxidizing agent. At 90 K, the compound looks like a reddish-brown liquid and as an oil at 77  K.[3]

At 77 K, the compound is insoluble in liquid N
2
, soluble in liquid O
2
and CH
4
. At 65 K, it is soluble in liquid OF
2
.[3]

References

  1. Streng, A. G.; Grosse, A. V. (January 1966). "Two New Fluorides of Oxygen, O5F2 and O6F2 1,2". Journal of the American Chemical Society 88 (1): 169–170. doi:10.1021/ja00953a035. https://pubs.acs.org/doi/abs/10.1021/ja00953a035. Retrieved 19 May 2023. 
  2. Bailar, John Christian; Trotman-Dickenson, A. F. (1973) (in en). Comprehensive Inorganic Chemistry: Ge, Sn, Pb, Group VB, Group VIB, Group VIIB. Pergamon Press. p. 764. ISBN 978-0-08-017275-0. https://books.google.com/books?id=DM_VAAAAMAAJ&q=pentaoxygen+difluoride. Retrieved 19 May 2023. 
  3. 3.0 3.1 3.2 (in en) F Fluorine: Compounds with Oxygen and Nitrogen. Springer Science & Business Media. 29 June 2013. p. 134. ISBN 978-3-662-06339-2. https://books.google.com/books?id=rpfsCAAAQBAJ&dq=pentaoxygen+difluoride&pg=PR14. Retrieved 19 May 2023.