Chemistry:Lithium hexafluorotitanate

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Lithium hexafluorotitanate
Names
Other names
dilithium hexafluorotitanate, titanium lithium hexafluoride
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 242-866-4
Properties
F6Li2Ti
Molar mass 175.74 g·mol−1
Appearance solid
Density 2.89 g/cm3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

Lithium hexafluorotitanate is an inorganic compound of lithium, fluorine, and titanium with the chemical formula Li
2
TiF
6
.[1][2]

Synthesis

Interaction of titanium hydroxide or oxide and lithium fluoride with hydrofluoric acid.[3]

Physical properties

The compound forms crystals of tetragonal crystal system with a space group of P42/mnm (no. 136).[4]

Chemical properties

The compound forms hydrates Li
3
TiF
6
*xH
2
O
.[5][6]

References

  1. "Lithium Hexafluorotitanate" (in en). American Elements. https://www.americanelements.com/lithium-hexafluorotitanate-19193-50-1. 
  2. "LITHIUM HEXAFLUOROTITANATE" (in en). chemsrc.com. https://www.chemsrc.com/en/cas/19193-50-1_382493.html. 
  3. Tikhomirova, E. L.; Nesterov, D. P.; Gromov, O. G.; Lokshin, E. P.; Kalinnikov, V. T. (1 June 2013). "Synthesis of lithium hexafluorotitanate" (in en). Russian Journal of Applied Chemistry 86 (6): 831–835. doi:10.1134/S1070427213060074. ISSN 1608-3296. https://link.springer.com/article/10.1134/S1070427213060074. Retrieved 16 February 2024. 
  4. "mp-7603". Materials Project. https://legacy.materialsproject.org/materials/mp-7603/. 
  5. Marseglia, E. A.; Brown, I. D. (15 June 1973). "Lithium hexafluorotitanate dihydrate and lithium hexafluorostannate dihydrate" (in en). Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry 29 (6): 1352–1354. doi:10.1107/S0567740873004498. ISSN 0567-7408. Bibcode1973AcCrB..29.1352M. https://scripts.iucr.org/cgi-bin/paper?S0567740873004498. Retrieved 16 February 2024. 
  6. Nyquist, Richard A.; Putzig, Curtis L.; Kagel, Ronald O.; Leugers, M. Anne (28 December 1971) (in en). Handbook of Infrared and Raman Spectra of Inorganic Compounds and Organic Salts: Infrared Spectra of Inorganic Compounds. Academic Press. p. 32. ISBN 978-0-12-523450-4. https://books.google.com/books?id=D3Aeq3sq2PQC&dq=Lithium+hexafluorotitanate&pg=PA32. Retrieved 16 February 2024.