Chemistry:6,14-Endoethenotetrahydrooripavine
From HandWiki
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| IUPAC name
(4R,7S,7aR,12bR)-7-Methoxy-3-methyl-2,3,4,4a,7,7a-hexahydro-1H-4al5-4a,7-ethano-4,12-methanobenzofuro[3,2-e]isoquinolin-9-ol
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3D model (JSmol)
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PubChem CID
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| Properties | |
| C20H23NO3 | |
| Molar mass | 325.408 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Tracking categories (test):
6,14-Endoethenotetrahydrooripavine is the central nucleus, or backbone, of a class of morphinan opioids known as the Bentley compounds and may be considered their "privileged scaffold".[1][2] These include but are not limited to etorphine and buprenorphine. They usually have thebaine or oripavine as their precursor in their syntheses (and are thus termed "thevinols" and "orvinols", respectively).
See also
References
- ↑ Bentley, Kenneth W.; Hardy, Denis G. (June 1967). "Novel analgesics and molecular rearrangements in the morphine-thebaine group. III. Alcohols of the 6,14-endo-ethenotetrahydrooripavine series and derived analogs of N-allylnormorphine and -norcodeine" (in en). Journal of the American Chemical Society 89 (13): 3281–3292. doi:10.1021/ja00989a032. ISSN 0002-7863. PMID 6042764. https://pubs.acs.org/doi/abs/10.1021/ja00989a032.
- ↑ PubChem. "6,14-Endoethenotetrahydrooripavine" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/59866315.
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